Entanglement of two-qubit photon beam by magnetic field

We have studied the possibility of affecting the entanglement measure of 2-qubit system consisting of two photons with different fixed frequencies but with two arbitrary linear polarizations, moving in the same direction, by the help of an applied external magnetic field. The interaction between the magnetic field and the photons in our model is achieved through intermediate electrons that interact with both the photons and the magnetic field. The possibility of exact theoretical analysis of this scheme is based on known exact solutions that describe the interaction of an electron subjected to an external magnetic field (or a medium of electrons not interacting with each other) with a quantized field of two photons. We adapt these exact solutions to the case under consideration. Using explicit wave functions for the resulting electromagnetic field, we calculate the entanglement measure of the photon beam as a function of the applied magnetic field and parameters of the electron medium

Synthesis of pi-conjugated systems bearing thiophene and pyrrole heterocycles through palladium catalyzed cross-coupling reactions.

A series of thienylpyrroles and bithienylpyrroles together with their formyl derivatives 5aed were synthesized using commercially or readily available coupling components, through three different palladium catalyzed cross-coupling reactions (Suzuki-Miyaura, Stille and decarboxylative coupling). The synthesis of compounds 5 via the Suzuki-Miyaura reaction produced the title compounds in better yields than the other coupling reactions, while, decarboxylative coupling resulted in the lower yields. UV-visible and 1H NMR studies confirm the existence of significant intramolecular charge transfer (ICT) from the donor pyrrole heterocycle to the acceptor group and a high polarizability of the whole pi-conjugated systems. Together these characteristics indicate their strong potential as versatile precursors for the preparation of push-pull heterocyclic compounds for optical applications.The authors thank the Fundação para a Ciência e Tecnologia (Portugal) and FEDER-COMPETE for financial support through the Centro de Química – Universidade do Minho, Projects PTDC/QUI/66251/2006 (FCOMP-01-0124-FEDER-007429), CQ/UM PEst-C/QUI/UI0686/2013 (FCOMP-01-0124-FEDER-037302) and a PhD grant to M. C. R. Castro (SFRH/BD/78037/2011). The NMR spectrometer Bruker Avance III 400 is part of the National NMR Network and was purchased within the framework of the National Program for Scientific Re-equipment, with funds from FCT

Analysis of process variables via CFD to evaluate the performance of a FCC riser

Feedstock conversion and yield products are studied through a 3D model simulating the main reactor of the fluid catalytic cracking (FCC) process. Computational fluid dynamic (CFD) is used with Eulerian-Eulerian approach to predict the fluid catalytic cracking behavior. The model considers 12 lumps with catalyst deactivation by coke and poisoning by alkaline nitrides and polycyclic aromatic adsorption to estimate the kinetic behavior which, starting from a given feedstock, produces several cracking products. Different feedstock compositions are considered. The model is compared with sampling data at industrial operation conditions. The simulation model is able to represent accurately the products behavior for the different operating conditions considered. All the conditions considered were solved using a solver ANSYS CFX 14.0. The different operation process variables and hydrodynamic effects of the industrial riser of a fluid catalytic cracking (FCC) are evaluated. Predictions from the model are shown and comparison with experimental conversion and yields products are presented; recommendations are drawn to establish the conditions to obtain higher product yields in the industrial process

Spin and pseudospin symmetries in the antinucleon spectrum of nuclei

Spin and pseudospin symmetries in the spectra of nucleons and antinucleons are studied in a relativistic mean-field theory with scalar and vector Woods-Saxon potentials, in which the strength of the latter is allowed to change. We observe that, for nucleons and antinucleons, the spin symmetry is of perturbative nature and it is almost an exact symmetry in the physical region for antinucleons. The opposite situation is found in the pseudospin symmetry case, which is better realized for nucleons than for antinucleons, but is of dynamical nature and cannot be viewed in a perturbative way both for nucleons and antinucleons. This is shown by computing the spin-orbit and pseudospin-orbit couplings for selected spin and pseudospin partners in both spectra.Comment: 8 figures, uses revtex 4.1 macro

Signatures of nematic quantum critical fluctuations in the Raman spectra of lightly doped cuprates

We consider the lightly doped cuprates Y$_{0.97}$Ca$_{0.03}$BaCuO$_{6.05}$ and La$_{2-x}$Sr$_x$CuO$_4$ (with $x=0.02$,0.04), where the presence of a fluctuating nematic state has often been proposed as a precursor of the stripe (or, more generically, charge-density wave) phase, which sets in at higher doping. We phenomenologically assume a quantum critical character for the longitudinal and transverse nematic, and for the charge-ordering fluctuations, and investigate the effects of these fluctuations in Raman spectra. We find that the longitudinal nematic fluctuations peaked at zero transferred momentum account well for the anomalous Raman absorption observed in these systems in the $B_{2g}$ channel, while the absence of such effect in the $B_{1g}$ channel may be due to the overall suppression of Raman response at low frequencies, associated with the pseudogap. While in Y$_{0.97}$Ca$_{0.03}$BaCuO$_{6.05}$ the low-frequency lineshape is fully accounted by longitudinal nematic collective modes alone, in La$_{2-x}$Sr$_x$CuO$_4$ also charge-ordering modes with finite characteristic wavevector are needed to reproduce the shoulders observed in the Raman response. This different involvement of the nearly critical modes in the two materials suggests a different evolution of the nematic state at very low doping into the nearly charge-ordered state at higher doping.Comment: 12 pages with 10 figures, to appear in Phys. Rev. B 201

Dirac Fermion Confinement in Graphene

We study the problem of Dirac fermion confinement in graphene in the presence of a perpendicular magnetic field B. We show, analytically and numerically, that confinement leads to anomalies in the electronic spectrum and to a magnetic field dependent crossover from \sqrt{B}, characteristic of Dirac-Landau level behavior, to linear in B behavior, characteristic of confinement. This crossover occurs when the radius of the Landau level becomes of the order of the width of the system. As a result, we show that the Shubnikov-de Haas oscillations also change as a function of field, and lead to a singular Landau plot. We show that our theory is in excellent agreement with the experimental data.Comment: 4 pages, 6 figure

The influence of statistical properties of Fourier coefficients on random surfaces

Many examples of natural systems can be described by random Gaussian surfaces. Much can be learned by analyzing the Fourier expansion of the surfaces, from which it is possible to determine the corresponding Hurst exponent and consequently establish the presence of scale invariance. We show that this symmetry is not affected by the distribution of the modulus of the Fourier coefficients. Furthermore, we investigate the role of the Fourier phases of random surfaces. In particular, we show how the surface is affected by a non-uniform distribution of phases